Information card for entry 7103281

Structure parameters

• Formula: C22 H51 Co N2 P2 Si
• Calculated formula: C22 H51 Co N2 P2 Si
• SMILES: C(C)(C)(N1[Co]23[N]([Si]1(C)C)(CC[P]2(C(C)C)C(C)C)CC[P]3(C(C)C)C(C)C)C
• Title of publication: Reactivity of a Co(i) [N(2)P(2)] complex with azides: evidence for a transient Co(iii) imido species.
• Authors of publication: Chomitz, Wayne A; Arnold, John
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 31
• Pages of publication: 3648 - 3650
• a: 14.742 ± 0.004 Å
• b: 17.148 ± 0.005 Å
• c: 11.265 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2847.6 ± 1.3 ų
• Cell temperature: 244 ± 2 K
• Ambient diffraction temperature: 244 ± 2 K
• Number of distinct elements: 6
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.1017
• Residual factor for significantly intense reflections: 0.0528
• Weighted residual factors for significantly intense reflections: 0.1429
• Weighted residual factors for all reflections included in the refinement: 0.1668
• Goodness-of-fit parameter for all reflections included in the refinement: 1.033
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No