Information card for entry 7103486

Structure parameters

• Formula: C31 H42 Ge N2
• Calculated formula: C31 H42 Ge N2
• SMILES: [Ge]12N(C(=C)C(C(=[N]1c1c(cccc1C(C)C)C(C)C)C)C=C2)c1c(cccc1C(C)C)C(C)C
• Title of publication: Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C-H bond activation.
• Authors of publication: Yao, Shenglai; van Wüllen, Christoph; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 42
• Pages of publication: 5393 - 5395
• a: 10.5367 ± 0.0004 Å
• b: 12.484 ± 0.0005 Å
• c: 42.662 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5611.8 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1361
• Residual factor for significantly intense reflections: 0.042
• Weighted residual factors for significantly intense reflections: 0.0584
• Weighted residual factors for all reflections included in the refinement: 0.0705
• Goodness-of-fit parameter for all reflections included in the refinement: 0.721
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No