Information card for entry 7104101

Structure parameters

• Formula: C40 H60 Cl2 In3 Rh
• Calculated formula: C40 H60 Cl2 In3 Rh
• SMILES: [Rh]12345([c]6(C)[c]3([c]2([c]4([c]56C)C)C)C)([In]([Cl][In]34561[c]1([c]6(C)[c]3([c]4(C)[c]51C)C)C)(Cl)C1(C(=C(C(=C1C)C)C)C)C)[In]1234[c]5([c]1(C)[c]2([c]3([c]45C)C)C)C
• Title of publication: Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal‒group 13 metal bond formation
• Authors of publication: Steinke, Tobias; Gemel, Christian; Cokoja, Mirza; Winter, Manuela; Fischer, Roland A.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 9
• Pages of publication: 1066 - 1067
• a: 10.732 ± 0.019 Å
• b: 21.72 ± 0.04 Å
• c: 35.49 ± 0.05 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8272 ± 24 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 5
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0906
• Residual factor for significantly intense reflections: 0.0558
• Weighted residual factors for significantly intense reflections: 0.1241
• Weighted residual factors for all reflections included in the refinement: 0.1392
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No