Information card for entry 7104911

Structure parameters

• Formula: C21 H44 Li N3 Si2
• Calculated formula: C21 H44 Li N3 Si2
• SMILES: [Li]1(N([Si](C)(C)C)[Si](C)(C)C)[N]23CCCC[C@@H]3[C@@H]3C[N]41CCCC[C@@H]4[C@H](C2)C3
• Title of publication: Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.
• Authors of publication: Clark, Natalie M; García-Alvarez, Pablo; Kennedy, Alan R; O'Hara, Charles T; Robertson, Gemma M
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2009
• Journal issue: 39
• Pages of publication: 5835 - 5837
• a: 7.6371 ± 0.0003 Å
• b: 9.103 ± 0.0003 Å
• c: 10.5163 ± 0.0004 Å
• α: 111.657 ± 0.002°
• β: 106.12 ± 0.002°
• γ: 97.915 ± 0.002°
• Cell volume: 628.71 ± 0.04 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0632
• Residual factor for significantly intense reflections: 0.0504
• Weighted residual factors for significantly intense reflections: 0.1318
• Weighted residual factors for all reflections included in the refinement: 0.1416
• Goodness-of-fit parameter for all reflections included in the refinement: 1.091
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No