Information card for entry 7105238

Structure parameters

• Common name: (Pt(IMes*)(IMes)Me)
• Formula: C43 H50 N4 Pt
• Calculated formula: C43 H50 N4 Pt
• SMILES: [Pt]1(=C2N(C=CN2c2c(cc(cc2C)C)C)c2c(cc(cc2C)C)C)(=C2N(C=CN2c2c(cc(cc2C)C)C1)c1c(cc(cc1C)C)C)C
• Title of publication: Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(II)-dimethyl moiety.
• Authors of publication: Fortman, George C; Scott, Natalie M; Linden, Anthony; Stevens, Edwin D; Dorta, Reto; Nolan, Steven P
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2010
• Journal volume: 46
• Journal issue: 7
• Pages of publication: 1050 - 1052
• a: 10.7787 ± 0.0005 Å
• b: 20.0707 ± 0.0009 Å
• c: 17.2875 ± 0.0008 Å
• α: 90°
• β: 91.064 ± 0.001°
• γ: 90°
• Cell volume: 3739.3 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0548
• Residual factor for significantly intense reflections: 0.0422
• Weighted residual factors for significantly intense reflections: 0.0831
• Weighted residual factors for all reflections included in the refinement: 0.0858
• Goodness-of-fit parameter for all reflections included in the refinement: 1.11
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No