Information card for entry 7105725

Structure parameters

• Common name: N-(7-methyl-6-oxo-6,7-dihydro-(1,3)dioxolo(4,5-f)benzofuran-7- yl)-P,P-diphenylphosphinic amide
• Chemical name: N-(7-methyl-6-oxo-6,7-dihydro-[1,3]dioxolo[4,5-f]benzofuran-7-yl)- P,P-diphenylphosphinic amide
• Formula: C22 H18 N O5 P
• Calculated formula: C22 H18 N O5 P
• Title of publication: Asymmetric Total Synthesis of (+)-Fumimycin via 1,2-Addition to Ketimines
• Authors of publication: Patrick Gross; Filipp Furche; Martin Nieger; Stefan Brase
• Journal of publication: Chem.Commun.
• Year of publication: 2010
• Journal volume: 46
• Pages of publication: 9215
• a: 5.894 ± 0.001 Å
• b: 10.203 ± 0.002 Å
• c: 16.399 ± 0.003 Å
• α: 97.76 ± 0.02°
• β: 96.88 ± 0.02°
• γ: 99.17 ± 0.02°
• Cell volume: 954.5 ± 0.3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0934
• Residual factor for significantly intense reflections: 0.0643
• Weighted residual factors for significantly intense reflections: 0.1583
• Weighted residual factors for all reflections included in the refinement: 0.177
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No