Information card for entry 7105811

Structure parameters

• Chemical name: 2,5-di-(dimethyl-aminomethylidenyl)-cylcopentan-1-ylidene-chloro- bis(triphenylphosphine)platinum(ii) tetrafluoroborate dichloromethane solute
• Formula: C48 H50 B Cl3 F4 N2 P2 Pt
• Calculated formula: C48 H50 B Cl3 F4 N2 P2 Pt
• SMILES: [B](F)(F)(F)[F-].C1(=[Pt](Cl)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)/C(=C/N(C)C)CC/C/1=C\N(C)C.C(Cl)Cl
• Title of publication: Metal complexes with carbene ligands stabilized by lateral enamines
• Authors of publication: Manuel Alcarazo; Karin Radkowski; Richard Goddard; Alois Furstner
• Journal of publication: Chem.Commun.
• Year of publication: 2011
• Journal volume: 47
• Pages of publication: 776
• a: 15.9121 ± 0.0016 Å
• b: 14.9665 ± 0.0015 Å
• c: 18.7527 ± 0.0019 Å
• α: 90°
• β: 96.182 ± 0.002°
• γ: 90°
• Cell volume: 4440 ± 0.8 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0405
• Residual factor for significantly intense reflections: 0.0286
• Weighted residual factors for significantly intense reflections: 0.0764
• Weighted residual factors for all reflections included in the refinement: 0.089
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No