Information card for entry 7105813

Structure parameters

• Common name: (N-(2,6-diisopropylphenyl)-N-((1Z,3E)-3-(N-(2,6- diisopropylphenyl)-N-((1Z,3E)-3-(N-(2-(N-(2-(N,N-dimethylamino)ethyl)-N- methylamino)ethyl)imino)-1-methylbut-1-enyl)amido- kappaN$1!,N$2!,N$3!)(N-(2,6-diisopropylphenyl)amido)\ (trimethylsilylmethyl)scandium(iii)
• Chemical name: {<i>N</i>-(2,6-diisopropylphenyl)-<i>N</i>-{(1<i>Z</i>,3<i>E</i>)-3- {<i>N</i>-(2,6-diisopropylphenyl)-<i>N</i>-{(1<i>Z</i>,3<i>E</i>)- 3-[<i>N</i>-(2-{<i>N</i>-[2-(<i>N</i>,<i>N</i>-dimethylamino)ethyl]- <i>N</i>-methylamino}ethyl)imino]-1-methylbut-1-enyl}amido- κ<i>N</i>^1^,<i>N</i>^2^,<i>N</i>^3^}[<i>N</i>-(2,6-diisopropylphenyl)amido]\ (trimethylsilylmethyl)scandium(III)
• Formula: C40 H70 N5 Sc Si
• Calculated formula: C40 H70 N5 Sc Si
• Title of publication: The scandium terminal imido complexes induced C-H bond selenation and the formation of Sc-Se bond
• Authors of publication: Erli Lu; Jiaxiang Chu; Yaofeng Chen; Maxim Borzov; Guangyu Li
• Journal of publication: Chem.Commun.
• Year of publication: 2011
• Journal volume: 47
• Pages of publication: 743
• a: 9.46 ± 0.0007 Å
• b: 23.0011 ± 0.0016 Å
• c: 20.5013 ± 0.0014 Å
• α: 90°
• β: 101.978 ± 0.002°
• γ: 90°
• Cell volume: 4363.8 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1061
• Residual factor for significantly intense reflections: 0.063
• Weighted residual factors for significantly intense reflections: 0.1492
• Weighted residual factors for all reflections included in the refinement: 0.1666
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No