Information card for entry 7106147

Structure parameters

• Formula: C69 H66 B2 F24 N P2 Rh
• Calculated formula: C69 H66 B2 F24 N P2 Rh
• Title of publication: Tuning the [L2RhH3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes
• Authors of publication: Romaeo Dallanegra Alasdair P. M. Robertson Adrian B. Chaplin Ian Manners Andrew S. Weller
• Journal of publication: Chem.Commun.
• Year of publication: 2011
• Journal volume: 47
• Pages of publication: 3763
• a: 14.9418 ± 0.0001 Å
• b: 19.267 ± 0.0002 Å
• c: 25.1468 ± 0.0002 Å
• α: 90°
• β: 91.2143 ± 0.0003°
• γ: 90°
• Cell volume: 7237.73 ± 0.11 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0553
• Residual factor for significantly intense reflections: 0.0427
• Weighted residual factors for significantly intense reflections: 0.1007
• Weighted residual factors for all reflections included in the refinement: 0.1072
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No