Information card for entry 7107072

Structure parameters

• Formula: C22 H24 F12 N6 O2 Os P2 S
• Calculated formula: C22 H24 F12 N6 O2 Os P2 S
• Title of publication: A bis-bipyridine osmium(II) complex with an N,S-chelating 2-aminoethanesulfinate: photoinduced conversion of amine to imine donor group by air oxidation
• Authors of publication: Motoshi Tamura; Kiyoshi Tsuge; Asako Igashira-Kamiyama; Takumi Konno
• Journal of publication: Chem.Commun.
• Year of publication: 2011
• Journal volume: 47
• Pages of publication: 12464
• a: 15.917 ± 0.0003 Å
• b: 9.4043 ± 0.0002 Å
• c: 20.2031 ± 0.0005 Å
• α: 90°
• β: 100.515 ± 0.001°
• γ: 90°
• Cell volume: 2973.38 ± 0.11 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0307
• Residual factor for significantly intense reflections: 0.0262
• Weighted residual factors for significantly intense reflections: 0.0618
• Weighted residual factors for all reflections included in the refinement: 0.0637
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No