Information card for entry 7110845

Structure parameters

• Common name: 2B
• Formula: C32 H40 Mo N4 Si2
• Calculated formula: C32 H40 Mo N4 Si2
• SMILES: [Mo]12(N([Si](C)(C)C)c3ccccc3N1[Si](C)(C)C)(=Nc1ccccc1)N(c1ccccc1)C2(c1ccccc1)C
• Title of publication: Molybdenum η2-imine complex formation and the reductive coupling of imines
• Authors of publication: Cameron, Tom M.; Ortiz, Carlos G.; Abboud, Khalil A.; Boncella, James M.; Baker, R. Tom; Scott, Brian L.
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 7
• Pages of publication: 573
• a: 9.8565 ± 0.0005 Å
• b: 18.8443 ± 0.0008 Å
• c: 17.9089 ± 0.0008 Å
• α: 90°
• β: 104.652 ± 0.001°
• γ: 90°
• Cell volume: 3218.2 ± 0.3 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0647
• Residual factor for significantly intense reflections: 0.0431
• Weighted residual factors for significantly intense reflections: 0.0774
• Weighted residual factors for all reflections included in the refinement: 0.0831
• Goodness-of-fit parameter for all reflections included in the refinement: 1.225
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No