Information card for entry 7111085

Structure parameters

• Formula: C130 H90 N3 O22 P7 Rh10
• Calculated formula: C130 H90 N3 O22 P7 Rh10
• Title of publication: Deactivation of a [PPN][Rh(CO)4]-based catalytic system [PPN+ = (PPh3)2N+]. The first decomposition reaction of PPN+ and the formation of [Rh10P(CO)22]3−
• Authors of publication: Ragaini, Fabio; Sironi, Angelo; Fumagalli, Alessandro
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 21
• Pages of publication: 2117
• a: 16.2084 ± 0.0007 Å
• b: 16.3039 ± 0.0007 Å
• c: 23.9367 ± 0.0011 Å
• α: 91.241 ± 0.001°
• β: 94.88 ± 0.001°
• γ: 90.067 ± 0.001°
• Cell volume: 6301.1 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.098
• Residual factor for significantly intense reflections: 0.0634
• Weighted residual factors for significantly intense reflections: 0.1494
• Weighted residual factors for all reflections included in the refinement: 0.1696
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No