Information card for entry 7111154

Structure parameters

• Formula: C73 H63 B F24 N3 O Rh
• Calculated formula: C73 H63 B F27 N3 O Rh
• Title of publication: Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions
• Authors of publication: Dias, Eric L.; Brookhart, Maurice; White, Peter S.
• Journal of publication: Chemical Communications
• Year of publication: 2001
• Journal issue: 5
• Pages of publication: 423
• a: 13.3839 ± 0.0006 Å
• b: 16.3962 ± 0.0007 Å
• c: 16.8506 ± 0.0007 Å
• α: 80.16 ± 0.001°
• β: 79.835 ± 0.001°
• γ: 86.89 ± 0.001°
• Cell volume: 3585.1 ± 0.3 ų
• Cell temperature: 193 K
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.053
• Residual factor for significantly intense reflections: 0.053
• Weighted residual factors for all reflections: 0.056
• Weighted residual factors for significantly intense reflections: 0.056
• Goodness-of-fit parameter for significantly intense reflections: 2.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MolybdenumKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No