Information card for entry 7112009

Structure parameters

• Formula: C280 H436 Ag70 B10 F40 N4 O73 P2 W18
• Calculated formula: C280 H426 Ag70 B10 F40 N4 O73 P2 W18
• Title of publication: Ag70(PW9O34)2(tBuC[triple bond, length as m-dash]C)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions
• Authors of publication: Zhan-Guo Jiang; Kang Shi; Yu-Mei Lin; Quan-Ming Wang
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 2353
• a: 24.1791 ± 0.0005 Å
• b: 22.448 ± 0.0005 Å
• c: 39.8847 ± 0.0012 Å
• α: 90°
• β: 106.426 ± 0.003°
• γ: 90°
• Cell volume: 20764.8 ± 0.9 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0915
• Residual factor for significantly intense reflections: 0.0532
• Weighted residual factors for significantly intense reflections: 0.0864
• Weighted residual factors for all reflections included in the refinement: 0.0971
• Goodness-of-fit parameter for all reflections included in the refinement: 0.978
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No