Information card for entry 7113520

Structure parameters

• Formula: C39 H38 Ge N2 O8 P2 Si2 W2
• Calculated formula: C39 H38 Ge N2 O8 P2 Si2 W2
• SMILES: [W]([Ge]12[W]3([N]([Si](C)(C)C)=P([C@]13P(=[N]2[Si](C)(C)C)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: A novel synthesis of metallogermacyclopropane and molybdenum bis(iminophosphorano)carbene complexes from bisgermavinylidene
• Authors of publication: Leung, Wing-Por; So, Cheuk-Wai; Wang, Jin-Zhi; Mak, Thomas C. W.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 2
• Pages of publication: 248 - 249
• a: 10.9208 ± 0.0015 Å
• b: 19.945 ± 0.003 Å
• c: 20.951 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4563.4 ± 1.1 ų
• Cell temperature: 294 ± 2 K
• Ambient diffraction temperature: 294 ± 2 K
• Number of distinct elements: 8
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.037
• Residual factor for significantly intense reflections: 0.0277
• Weighted residual factors for significantly intense reflections: 0.0628
• Weighted residual factors for all reflections included in the refinement: 0.0836
• Goodness-of-fit parameter for all reflections included in the refinement: 1.09
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Duplicate of: 7103936
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No