Information card for entry 7113601

Structure parameters

• Formula: C76 H100 Li N4 O4 Sm
• Calculated formula: C76 H100 Li N4 O4 Sm
• Title of publication: Lanthanide complexes derived from (R)-1,1'-binaphthyl-2,2'-bis(neopentylamine) ‒ {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) ‒ novel catalysts for enantioselective intramolecular hydroamination
• Authors of publication: Collin, Jacqueline; Daran, Jean-Claude; Schulz, Emmanuelle; Trifonov, Alexander
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 24
• Pages of publication: 3048 - 3049
• a: 11.1019 ± 0.0007 Å
• b: 25.0568 ± 0.0014 Å
• c: 25.2362 ± 0.0014 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7020.2 ± 0.7 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0512
• Residual factor for significantly intense reflections: 0.0447
• Weighted residual factors for significantly intense reflections: 0.0879
• Weighted residual factors for all reflections included in the refinement: 0.09
• Goodness-of-fit parameter for all reflections included in the refinement: 1.068
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Duplicate of: 7103915
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No