Information card for entry 7113696

Structure parameters

• Common name: (CGC)arsenic chloride
• Chemical name: t-butyl(dimetyl(tetra-methylcyclopentadienyl)silyl)amido arsenic chloride
• Formula: C15 H27 As Cl N Si
• Calculated formula: C15 H27 As Cl N Si
• SMILES: C12=C(C(=C(C1(C)[As](N(C(C)(C)C)[Si]2(C)C)Cl)C)C)C
• Title of publication: The contrasting behaviour of bridged amido-cyclopentadienyl (constrained geometry) group 15 chlorides and cations derived therefrom
• Authors of publication: Wiacek, Robert J.; Macdonald, Charles L. B.; Jones, Jamie N.; Pietryga, Jeffrey M.; Cowley, Alan H.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 3
• Pages of publication: 430 - 431
• a: 6.953 ± 0.005 Å
• b: 17.258 ± 0.005 Å
• c: 14.991 ± 0.005 Å
• α: 90 ± 0.005°
• β: 91.669 ± 0.005°
• γ: 90 ± 0.005°
• Cell volume: 1798.1 ± 1.5 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.035
• Residual factor for significantly intense reflections: 0.0274
• Weighted residual factors for significantly intense reflections: 0.0549
• Weighted residual factors for all reflections included in the refinement: 0.0572
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Duplicate of: 7103965
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No