Information card for entry 7113698

Structure parameters

• Common name: (CGC)phosphorous chloride
• Chemical name: t-butyl(dimetyl(tetra-methylcyclopentadienyl)silyl)amido phosporous chloride
• Formula: C15 H27 Cl N P Si
• Calculated formula: C15 H27 Cl N P Si
• SMILES: C12(C(=C(C(=C1P(N(C(C)(C)C)[Si]2(C)C)Cl)C)C)C)C
• Title of publication: The contrasting behaviour of bridged amido-cyclopentadienyl (constrained geometry) group 15 chlorides and cations derived therefrom
• Authors of publication: Wiacek, Robert J.; Macdonald, Charles L. B.; Jones, Jamie N.; Pietryga, Jeffrey M.; Cowley, Alan H.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 3
• Pages of publication: 430 - 431
• a: 14.969 ± 0.005 Å
• b: 15.3 ± 0.005 Å
• c: 15.506 ± 0.005 Å
• α: 90 ± 0.005°
• β: 90 ± 0.005°
• γ: 90 ± 0.005°
• Cell volume: 3551 ± 2 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P c a b
• Hall space group symbol: -P 2bc 2ac
• Residual factor for all reflections: 0.0482
• Residual factor for significantly intense reflections: 0.0335
• Weighted residual factors for significantly intense reflections: 0.0795
• Weighted residual factors for all reflections included in the refinement: 0.0855
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Duplicate of: 7103967
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No