Information card for entry 7114468

Structure parameters

• Common name: [{K(thf)2(Me3SiNCPhCHCPhNH)}2].2(thf)
• Formula: C60 H90 K2 N4 O6 Si2
• Calculated formula: C62 H74 K2 N4 O4 Si2
• SMILES: [K](NC(c1ccccc1)=CC(c1ccccc1)=N[Si](C)(C)C)([O]1CCCC1)[O]1CCCC1.C1CCCC1
• Title of publication: Syntheses and structures of structurally diverse potassium β-diketiminates derived from the ligand [{N(SiMe~3~)C(Ph)}~2~CH]^-^
• Authors of publication: Hitchcock, Peter B.; Lappert, Michael F.; Liu, Diang-Sheng; Sablong, Rafaël
• Journal of publication: Chemical Communications
• Year of publication: 2002
• Journal issue: 17
• Pages of publication: 1920 - 1921
• a: 9.8158 ± 0.0003 Å
• b: 10.7658 ± 0.0003 Å
• c: 15.208 ± 0.0005 Å
• α: 83.771 ± 0.002°
• β: 88.73 ± 0.002°
• γ: 89.386 ± 0.002°
• Cell volume: 1597.17 ± 0.08 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0633
• Residual factor for significantly intense reflections: 0.0565
• Weighted residual factors for significantly intense reflections: 0.1554
• Weighted residual factors for all reflections included in the refinement: 0.1614
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No