Information card for entry 7114470

Structure parameters

• Common name: [{K(thf)3(C3HPh2N2SiMe2)}2]
• Formula: C58 H82 K2 N4 O6 Si2
• Calculated formula: C58 H82 K2 N4 O6 Si2
• SMILES: [K]1([O]2CCCC2)([O]2CCCC2)([O]2CCCC2)[N](=C2c3ccccc3)[Si](C)(C)N(C(=C2)c2ccccc2)[K]([O]2CCCC2)([O]2CCCC2)([O]2CCCC2)[N](=C2c3ccccc3)[Si](C)(C)N1C(=C2)c1ccccc1
• Title of publication: Syntheses and structures of structurally diverse potassium β-diketiminates derived from the ligand [{N(SiMe~3~)C(Ph)}~2~CH]^-^
• Authors of publication: Hitchcock, Peter B.; Lappert, Michael F.; Liu, Diang-Sheng; Sablong, Rafaël
• Journal of publication: Chemical Communications
• Year of publication: 2002
• Journal issue: 17
• Pages of publication: 1920 - 1921
• a: 11.5035 ± 0.0004 Å
• b: 18.0757 ± 0.0007 Å
• c: 14.5585 ± 0.0006 Å
• α: 90°
• β: 100.978 ± 0.002°
• γ: 90°
• Cell volume: 2971.8 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1262
• Residual factor for significantly intense reflections: 0.0775
• Weighted residual factors for significantly intense reflections: 0.177
• Weighted residual factors for all reflections included in the refinement: 0.2051
• Goodness-of-fit parameter for all reflections included in the refinement: 1.007
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No