Information card for entry 7114567

Structure parameters

• Formula: C54 H70 Ge3 O4 P3 Pt3
• Calculated formula: C54 H70 Ge3 O4 P3 Pt3
• SMILES: [Pt]123([Ge](c4ccccc4)([Pt]452([Ge]([C]2(=[C]1(C(=O)OC)[Pt]352([Ge]4(c1ccccc1)c1ccccc1)[P](C)(C)C)C(=O)OC)(c1ccccc1)c1ccccc1)[P](C)(C)C)c1ccccc1)[P](C)(C)C.C(CCC)CC
• Title of publication: A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt‒Ge bond rather than the Pt‒Pt bond
• Authors of publication: Tanabe, Makoto; Tanaka, Kimiya; Omine, Shumpei; Osakada, Kohtaro
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2014
• Journal volume: 50
• Journal issue: 52
• Pages of publication: 6839 - 6842
• a: 12.053 ± 0.003 Å
• b: 23.593 ± 0.006 Å
• c: 20.308 ± 0.005 Å
• α: 90°
• β: 91.905 ± 0.004°
• γ: 90°
• Cell volume: 5772 ± 2 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0977
• Residual factor for significantly intense reflections: 0.0655
• Weighted residual factors for significantly intense reflections: 0.1313
• Weighted residual factors for all reflections included in the refinement: 0.1404
• Goodness-of-fit parameter for all reflections included in the refinement: 1.336
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No