Information card for entry 7114999

Structure parameters

• Common name: 6a
• Chemical name: Bis(N,N-dimethylacethydrazido-N,O)phenylsilicon trifluoromethylsulfonate
• Formula: C15 H23 F3 N4 O5 S Si
• Calculated formula: C15 H23 F3 N4 O5 S Si
• SMILES: [Si]12(c3ccccc3)([N](C)(C)N=C(C)O1)[N](C)(C)N=C(C)O2.C(F)(F)(F)S(=O)(=O)[O-]
• Title of publication: Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation–recombination of the Si–Cl bond
• Authors of publication: Kingston, Vijeyakumar; Gostevskii, Boris; Kalikhman, Inna; Kost, Daniel
• Journal of publication: Chemical Communications
• Year of publication: 2001
• Journal issue: 14
• Pages of publication: 1272
• a: 8.4678 ± 0.0015 Å
• b: 11.032 ± 0.002 Å
• c: 11.517 ± 0.002 Å
• α: 89.784 ± 0.005°
• β: 84.087 ± 0.005°
• γ: 75.05 ± 0.005°
• Cell volume: 1033.6 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.052
• Residual factor for significantly intense reflections: 0.0365
• Weighted residual factors for significantly intense reflections: 0.0941
• Weighted residual factors for all reflections included in the refinement: 0.1016
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No