Information card for entry 7115001

Structure parameters

• Formula: C56 H46 Ag2 Cl2 N20 O9 Ru2
• Calculated formula: C56 H44 Ag2 Cl2 N20 O9 Ru2
• SMILES: O.[Ag]([n]1c2c3n(cc[n]3[Ag]3)[Ru]45([n]6ccccc6N=[N]4c4ccccc4)([n]4ccccc4N=[N]5c4ccccc4)n2cc1)[n]1c2c4n(cc[n]34)[Ru]34([n]5ccccc5N=[N]3c3ccccc3)([n]3ccccc3N=[N]4c3ccccc3)n2cc1.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-]
• Title of publication: Unusual binding mode of the biimidazolate bridging ligand in two novel heteropolynuclear complexes with an M2Ag2 [M = Ru(ii) or Os(ii)] core
• Authors of publication: Majumdar, Partha; Kamar, Kunal K.; Goswami, Sreebrata; Castiñeiras, Alfonso
• Journal of publication: Chemical Communications
• Year of publication: 2001
• Journal issue: 14
• Pages of publication: 1292
• a: 34.037 ± 0.005 Å
• b: 19.467 ± 0.004 Å
• c: 10.0362 ± 0.0012 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6650 ± 1.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 52
• Hermann-Mauguin space group symbol: P n n a
• Hall space group symbol: -P 2a 2bc
• Residual factor for all reflections: 0.1778
• Residual factor for significantly intense reflections: 0.0782
• Weighted residual factors for significantly intense reflections: 0.2151
• Weighted residual factors for all reflections included in the refinement: 0.2514
• Goodness-of-fit parameter for all reflections included in the refinement: 0.876
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No