Information card for entry 7115078

Structure parameters

• Formula: C68 H55 I O2 P4 Pt3
• Calculated formula: C68 H55 I O2 P4 Pt3
• SMILES: [Pt]123([Pt]4([Pt]1([P](c1ccccc1)(c1ccccc1)c1ccccc1)([P]4(c1ccccc1)c1ccccc1)C3=O)([P](c1ccccc1)(c1ccccc1)c1ccccc1)C2=O)(I)[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Unexpected bonding similarities between the bridging metalloligands [MoCp(CO)3]− and [PtI(CO)2(PPh3)]− acting as 4-electron donors in metal clusters. Crystal structures of [Pt2Mo(μ-CO)3(μ-PPh2)Cp(PPh3)2] and [Pt3(μ-CO)2(μ-PPh2)I(PPh3)3]
• Authors of publication: Archambault, Christine; Bender, Robert; Braunstein, Pierre; Bouaoud, Salah-Eddine; Rouag, Djemel; Golhen, Stéphane; Ouahab, Lahcène
• Journal of publication: Chemical Communications
• Year of publication: 2001
• Journal issue: 9
• Pages of publication: 849
• a: 13.564 ± 0.012 Å
• b: 14.954 ± 0.006 Å
• c: 17.948 ± 0.008 Å
• α: 69.64 ± 0.03°
• β: 75.44 ± 0.04°
• γ: 63.98 ± 0.04°
• Cell volume: 3046 ± 3 ų
• Cell temperature: 253 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0742
• Residual factor for significantly intense reflections: 0.0397
• Weighted residual factors for significantly intense reflections: 0.0913
• Weighted residual factors for all reflections included in the refinement: 0.1026
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No