Information card for entry 7115120

Structure parameters

• Common name: sep699
• Formula: C18 H36 Cl2 P4 Pt Se4
• Calculated formula: C18 H36 Cl2 P4 Pt Se4
• SMILES: [Pt]12([Se]P3C4([Se]P5C3(C(C)(C)C)[Se]2(C5(P4[Se]1)C(C)(C)C))C(C)(C)C)(Cl)(Cl)[P](C)(C)C
• Title of publication: Syntheses of the novel cage compounds P3Se3C3But3 and P3Se4C3But3 and an unusual insertion reaction of [PtCl2(PMe3)] into the Se‒Se bond of the latter to give the six-coordinate Pt(iv) complex [PtCl2(PMe3)P3Se4C3But3]
• Authors of publication: Hitchcock, Peter B.; Nixon, John F.; Sakarya, Nurgün
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 18
• Pages of publication: 1745
• a: 34.5455 ± 0.0006 Å
• b: 34.5455 ± 0.0006 Å
• c: 16.7221 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 17282.4 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3 :H
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.0692
• Residual factor for significantly intense reflections: 0.0386
• Weighted residual factors for significantly intense reflections: 0.0825
• Weighted residual factors for all reflections included in the refinement: 0.095
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No