Information card for entry 7115155

Structure parameters

• Formula: C28 H56 Cl2 N2 Pd2 Si6
• Calculated formula: C22.512 H45.024 Cl1.608 N1.608 Pd1.608 Si5.216
• Title of publication: The first structurally characterised σ-bonded organonickel(i) compound. Crystal structures of [Ni{C(SiMe3)2(SiMe2C5H4N-2)}(PPh3)], [Ni{C(SiMe3)(SiMe2C5H4N-2)(SiMe2O)}]2 and [Pd(μ-Cl){C(SiMe3)2(SiMe2C5H4N-2)}]2
• Authors of publication: Eaborn, Colin; Hill, Michael S.; Hitchcock, Peter B.; Smith, J. David
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 8
• Pages of publication: 691
• a: 13.465 ± 0.005 Å
• b: 23.39 ± 0.012 Å
• c: 25.032 ± 0.009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7884 ± 6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1539
• Residual factor for significantly intense reflections: 0.0824
• Weighted residual factors for significantly intense reflections: 0.1875
• Weighted residual factors for all reflections included in the refinement: 0.2264
• Goodness-of-fit parameter for all reflections included in the refinement: 0.979
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No