Information card for entry 7116941

Structure parameters

• Chemical name: (2R*,6S*,Z)-6-hydroxy-6-(4-methoxyphenyl)-N-tosyl-2-(triisopropylsilyloxy)hex-3-enamide
• Formula: C28.84 H42.57 N O6 S Si
• Calculated formula: C28.844 H42.584 N O6 S Si
• Title of publication: Effective 1,5-stereocontrol in Pd(0)/InI promoted reactions of chiral N-Ts-4-vinylazetidin-2-ones with aldehydes. An efficient entry into nonracemic semi-protected (3Z)-2,6-anti-enediols
• Authors of publication: Urszula K. Klimczak; Bartosz K. Zambron
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 6796
• a: 15.627 ± 0.002 Å
• b: 13.4083 ± 0.0019 Å
• c: 15.769 ± 0.002 Å
• α: 90°
• β: 110.208 ± 0.008°
• γ: 90°
• Cell volume: 3100.7 ± 0.7 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1831
• Residual factor for significantly intense reflections: 0.1077
• Weighted residual factors for significantly intense reflections: 0.3289
• Weighted residual factors for all reflections included in the refinement: 0.3733
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No