Information card for entry 7117003

Structure parameters

• Formula: C51 H42 Bi Br2 N Si
• Calculated formula: C51 H42 Bi Br2 N Si
• SMILES: [Bi](Br)(Br)N([Si](c1ccccc1)(c1ccccc1)c1ccccc1)c1c(C(c2ccccc2)c2ccccc2)cc(cc1C(c1ccccc1)c1ccccc1)C
• Title of publication: Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene
• Authors of publication: Deepak Dange; Amelia Davey; Joseph A. B. Abdalla; Simon Aldridge; Cameron Jones
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 7128
• a: 10.3779 ± 0.0004 Å
• b: 12.172 ± 0.0004 Å
• c: 18.3157 ± 0.0007 Å
• α: 82.925 ± 0.002°
• β: 88.322 ± 0.002°
• γ: 66.682 ± 0.002°
• Cell volume: 2108 ± 0.14 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0358
• Residual factor for significantly intense reflections: 0.0289
• Weighted residual factors for significantly intense reflections: 0.0635
• Weighted residual factors for all reflections included in the refinement: 0.0655
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No