Information card for entry 7119222

Structure parameters

• Formula: C25 H44 Cl Ge N2 O P2 Rh
• Calculated formula: C25 H44 Cl Ge N2 O P2 Rh
• SMILES: [Rh]12([Ge]3(Cl)N(c4ccccc4N3C[P]1(C(C)(C)C)C(C)(C)C)C[P]2(C(C)(C)C)C(C)(C)C)C#[O]
• Title of publication: Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.
• Authors of publication: Álvarez-Rodríguez, Lucía; Brugos, Javier; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Polo, Diego
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2017
• Journal volume: 53
• Journal issue: 5
• Pages of publication: 893 - 896
• a: 9.9709 ± 0.0001 Å
• b: 20.7798 ± 0.0003 Å
• c: 14.2744 ± 0.0002 Å
• α: 90°
• β: 98.872 ± 0.001°
• γ: 90°
• Cell volume: 2922.17 ± 0.07 ų
• Cell temperature: 152 ± 2 K
• Ambient diffraction temperature: 152 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.031
• Residual factor for significantly intense reflections: 0.0266
• Weighted residual factors for significantly intense reflections: 0.0639
• Weighted residual factors for all reflections included in the refinement: 0.0666
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No