Information card for entry 7121664

Structure parameters

• Formula: C61 H48 B F24 P2 Rh Si
• Calculated formula: C61 H48 B F24 P2 Rh Si
• Title of publication: Small bite-angle 2-phosphinophosphinine ligands enable rhodium-catalysed hydroboration of carbonyls.
• Authors of publication: Newland, Robert J.; Lynam, Jason M.; Mansell, Stephen M.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 43
• Pages of publication: 5482 - 5485
• a: 13.2396 ± 0.0004 Å
• b: 14.6179 ± 0.0004 Å
• c: 18.0412 ± 0.0005 Å
• α: 98.298 ± 0.002°
• β: 102.651 ± 0.002°
• γ: 110.657 ± 0.003°
• Cell volume: 3092.5 ± 0.18 ų
• Cell temperature: 120 ± 0.1 K
• Ambient diffraction temperature: 120 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0695
• Residual factor for significantly intense reflections: 0.055
• Weighted residual factors for significantly intense reflections: 0.1258
• Weighted residual factors for all reflections included in the refinement: 0.134
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No