#------------------------------------------------------------------------------
#$Date: 2019-11-17 05:06:25 +0100 (Sun 17 de Nov de 2019) $
#$Revision: 228309 $
#$URL: svn://www.crystallography.net/cod/cif/7/12/17/7121737.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7121737
loop_
_publ_author_name
'Dhindsa, Jasveer S.'
'Maar, Ryan R.'
'Barbon, Stephanie M.'
'Olivia Avilés, María'
'Powell, Zachary K.'
'Lagugné-Labarthet, François'
'Gilroy, Joe B.'
_publ_section_title
;
 A π-conjugated inorganic polymer constructed from boron difluoride
 formazanates and platinum(ii) diynes.
;
_journal_issue                   50
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6899
_journal_page_last               6902
_journal_paper_doi               10.1039/c8cc02424c
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C66 H82 B2 F4 N8 P2 Pt'
_chemical_formula_weight         1342.04
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-03-08 deposited with the CCDC.
2018-05-17 downloaded from the CCDC.
;
_cell_angle_alpha                106.564(16)
_cell_angle_beta                 90.122(12)
_cell_angle_gamma                95.097(16)
_cell_formula_units_Z            1
_cell_length_a                   10.503(3)
_cell_length_b                   11.094(4)
_cell_length_c                   14.692(5)
_cell_measurement_reflns_used    9978
_cell_measurement_temperature    110
_cell_measurement_theta_max      35.15
_cell_measurement_theta_min      2.61
_cell_volume                     1633.7(9)
_computing_cell_refinement       SAINT
_computing_data_collection       Apex2
_computing_data_reduction        SAINT
_computing_molecular_graphics    Mercury
_computing_publication_material  cif2tables.py
_computing_structure_refinement  SHELXL
_computing_structure_solution    SHELXT
_diffrn_ambient_temperature      110
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            'Bruker Apex2'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.887
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Bruker Kappa Axis Apex2'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_unetI/netI     0.0700
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.887
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            64788
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.887
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         41.581
_diffrn_reflns_theta_min         2.393
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    2.253
_exptl_absorpt_correction_T_max  0.7482
_exptl_absorpt_correction_T_min  0.6627
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.364
_exptl_crystal_description       block
_exptl_crystal_F_000             688
_exptl_crystal_size_max          0.232
_exptl_crystal_size_mid          0.197
_exptl_crystal_size_min          0.057
_refine_diff_density_max         2.844
_refine_diff_density_min         -3.038
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     376
_refine_ls_number_reflns         19782
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0550
_refine_ls_R_factor_gt           0.0414
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0302P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0642
_refine_ls_wR_factor_ref         0.0676
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16988
_reflns_number_total             19782
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8cc02424c2.cif
_cod_data_source_block           3
_cod_depositor_comments          'Adding full bibliography for 7121737.cif.'
_cod_original_cell_volume        1633.7(10)
_cod_database_code               7121737
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.623
_shelx_estimated_absorpt_t_max   0.882
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pt1 Pt 1.000000 0.500000 0.500000 0.01314(2) Uani 1 2 d S . P
P1 P 0.88348(3) 0.51025(4) 0.36991(3) 0.01622(7) Uani 1 1 d . . .
F1 F 0.26181(8) 0.43569(8) 0.87490(7) 0.01993(18) Uani 1 1 d . . .
F2 F 0.32917(8) 0.36368(9) 0.99637(6) 0.02104(18) Uani 1 1 d . . .
N1 N 0.17541(10) 0.22809(12) 0.88259(8) 0.0148(2) Uani 1 1 d . . .
N2 N 0.19572(11) 0.11373(12) 0.88460(9) 0.0156(2) Uani 1 1 d . . .
N3 N 0.39107(10) 0.25896(11) 0.83744(8) 0.0130(2) Uani 1 1 d . . .
N4 N 0.40903(10) 0.14377(11) 0.83838(8) 0.0143(2) Uani 1 1 d . . .
B1 B 0.28932(14) 0.33237(16) 0.90213(11) 0.0149(3) Uani 1 1 d . . .
C1 C 0.31660(12) 0.08284(13) 0.87691(10) 0.0143(2) Uani 1 1 d . . .
C2 C 0.04564(12) 0.24327(15) 0.86192(10) 0.0168(3) Uani 1 1 d . . .
C3 C -0.00184(14) 0.35930(16) 0.89938(11) 0.0207(3) Uani 1 1 d . . .
H3 H 0.051998 0.429444 0.936631 0.025 Uiso 1 1 calc R U .
C4 C -0.12997(14) 0.37161(18) 0.88159(12) 0.0259(3) Uani 1 1 d . . .
H4 H -0.163719 0.450698 0.906579 0.031 Uiso 1 1 calc R U .
C5 C -0.20784(15) 0.26884(19) 0.82764(13) 0.0296(4) Uani 1 1 d . . .
H5 H -0.295367 0.277357 0.816865 0.035 Uiso 1 1 calc R U .
C6 C -0.15954(15) 0.1543(2) 0.78942(13) 0.0296(4) Uani 1 1 d . . .
H6 H -0.213683 0.084475 0.752076 0.035 Uiso 1 1 calc R U .
C7 C -0.03133(14) 0.14043(17) 0.80536(12) 0.0237(3) Uani 1 1 d . . .
H7 H 0.002859 0.062092 0.778068 0.028 Uiso 1 1 calc R U .
C8 C 0.46995(12) 0.30650(14) 0.77442(9) 0.0134(2) Uani 1 1 d . . .
C9 C 0.51961(12) 0.43261(14) 0.80220(10) 0.0157(2) Uani 1 1 d . . .
H9 H 0.492685 0.488890 0.859048 0.019 Uiso 1 1 calc R U .
C10 C 0.60876(13) 0.47543(14) 0.74616(10) 0.0166(3) Uani 1 1 d . . .
H10 H 0.642875 0.561367 0.765250 0.020 Uiso 1 1 calc R U .
C11 C 0.64925(13) 0.39378(14) 0.66179(10) 0.0162(3) Uani 1 1 d . . .
C12 C 0.59243(14) 0.26912(15) 0.63301(10) 0.0195(3) Uani 1 1 d . . .
H12 H 0.615161 0.213784 0.574314 0.023 Uiso 1 1 calc R U .
C13 C 0.50380(13) 0.22508(14) 0.68848(10) 0.0172(3) Uani 1 1 d . . .
H13 H 0.466440 0.140249 0.668191 0.021 Uiso 1 1 calc R U .
C14 C 0.34384(13) -0.03594(13) 0.89659(9) 0.0144(2) Uani 1 1 d . . .
C15 C 0.24622(14) -0.10797(14) 0.92711(10) 0.0176(3) Uani 1 1 d . . .
H15 H 0.162108 -0.081982 0.932881 0.021 Uiso 1 1 calc R U .
C16 C 0.27157(16) -0.21746(15) 0.94908(11) 0.0222(3) Uani 1 1 d . . .
H16 H 0.204768 -0.266051 0.969779 0.027 Uiso 1 1 calc R U .
C17 C 0.39409(17) -0.25595(15) 0.94087(11) 0.0234(3) Uani 1 1 d . . .
H17 H 0.411466 -0.330423 0.956440 0.028 Uiso 1 1 calc R U .
C18 C 0.49116(15) -0.18551(15) 0.90990(11) 0.0214(3) Uani 1 1 d . . .
H18 H 0.574807 -0.212644 0.903380 0.026 Uiso 1 1 calc R U .
C19 C 0.46705(14) -0.07556(14) 0.88832(10) 0.0174(3) Uani 1 1 d . . .
H19 H 0.534347 -0.027205 0.867917 0.021 Uiso 1 1 calc R U .
C20 C 0.75108(13) 0.43353(15) 0.60908(10) 0.0186(3) Uani 1 1 d . . .
C21 C 0.84373(13) 0.45960(15) 0.56633(10) 0.0173(3) Uani 1 1 d . . .
C22 C 0.71339(14) 0.45755(16) 0.36431(12) 0.0224(3) Uani 1 1 d . . .
H22A H 0.674261 0.506400 0.422963 0.027 Uiso 1 1 calc R U .
H22B H 0.673236 0.477858 0.310123 0.027 Uiso 1 1 calc R U .
C23 C 0.68143(15) 0.31696(16) 0.35337(12) 0.0237(3) Uani 1 1 d . . .
H23A H 0.699890 0.267763 0.287940 0.028 Uiso 1 1 calc R U .
H23B H 0.736646 0.291065 0.397811 0.028 Uiso 1 1 calc R U .
C24 C 0.54164(17) 0.28671(19) 0.37321(14) 0.0335(4) Uani 1 1 d . . .
H24A H 0.523119 0.338091 0.438010 0.040 Uiso 1 1 calc R U .
H24B H 0.486962 0.311427 0.327838 0.040 Uiso 1 1 calc R U .
C25 C 0.5065(2) 0.1483(2) 0.36535(14) 0.0410(5) Uani 1 1 d . . .
H25A H 0.415840 0.135341 0.378883 0.061 Uiso 1 1 calc R U .
H25B H 0.522469 0.096718 0.300906 0.061 Uiso 1 1 calc R U .
H25C H 0.558662 0.123408 0.411187 0.061 Uiso 1 1 calc R U .
C26 C 0.94818(15) 0.43156(16) 0.25526(11) 0.0221(3) Uani 1 1 d . . .
H26A H 0.879713 0.419441 0.206201 0.027 Uiso 1 1 calc R U .
H26B H 1.017393 0.489926 0.241520 0.027 Uiso 1 1 calc R U .
C27 C 1.00092(15) 0.30521(16) 0.24289(11) 0.0220(3) Uani 1 1 d . . .
H27A H 0.929374 0.239297 0.238792 0.026 Uiso 1 1 calc R U .
H27B H 1.055713 0.309655 0.298884 0.026 Uiso 1 1 calc R U .
C28 C 1.07926(15) 0.26936(16) 0.15285(12) 0.0249(3) Uani 1 1 d . . .
H28A H 1.023039 0.262819 0.097149 0.030 Uiso 1 1 calc R U .
H28B H 1.147935 0.337790 0.156237 0.030 Uiso 1 1 calc R U .
C29 C 1.1386(2) 0.1470(2) 0.13814(15) 0.0398(5) Uani 1 1 d . . .
H29A H 1.187084 0.129842 0.079624 0.060 Uiso 1 1 calc R U .
H29B H 1.196219 0.153313 0.192185 0.060 Uiso 1 1 calc R U .
H29C H 1.071195 0.078264 0.133036 0.060 Uiso 1 1 calc R U .
C30 C 0.88705(15) 0.67122(16) 0.35978(11) 0.0221(3) Uani 1 1 d . . .
H30A H 0.977280 0.702262 0.354526 0.027 Uiso 1 1 calc R U .
H30B H 0.841696 0.667626 0.299789 0.027 Uiso 1 1 calc R U .
C31 C 0.82873(16) 0.76772(17) 0.44047(12) 0.0266(3) Uani 1 1 d . . .
H31A H 0.873044 0.773026 0.501225 0.032 Uiso 1 1 calc R U .
H31B H 0.737415 0.739995 0.445380 0.032 Uiso 1 1 calc R U .
C32 C 0.84031(18) 0.89817(17) 0.42350(14) 0.0321(4) Uani 1 1 d . . .
H32A H 0.931852 0.924881 0.418436 0.038 Uiso 1 1 calc R U .
H32B H 0.796925 0.891601 0.362158 0.038 Uiso 1 1 calc R U .
C33 C 0.7832(2) 0.9989(2) 0.50132(18) 0.0480(6) Uani 1 1 d . . .
H33A H 0.793662 1.079660 0.486220 0.072 Uiso 1 1 calc R U .
H33B H 0.691948 0.974308 0.505789 0.072 Uiso 1 1 calc R U .
H33C H 0.827003 1.007620 0.562120 0.072 Uiso 1 1 calc R U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C21 Pt1 C21 180.0 . 2_766
C21 Pt1 P1 87.29(5) . 2_766
C21 Pt1 P1 92.71(5) 2_766 2_766
C21 Pt1 P1 92.71(5) . .
C21 Pt1 P1 87.29(5) 2_766 .
P1 Pt1 P1 180.0 2_766 .
C22 P1 C26 107.04(8) . .
C22 P1 C30 103.81(8) . .
C26 P1 C30 99.77(8) . .
C22 P1 Pt1 117.03(5) . .
C26 P1 Pt1 114.81(6) . .
C30 P1 Pt1 112.49(6) . .
N2 N1 C2 114.56(11) . .
N2 N1 B1 119.24(11) . .
C2 N1 B1 126.20(12) . .
N1 N2 C1 117.52(11) . .
N4 N3 C8 114.83(11) . .
N4 N3 B1 119.99(11) . .
C8 N3 B1 125.18(11) . .
N3 N4 C1 116.78(11) . .
F1 B1 F2 112.41(13) . .
F1 B1 N1 112.43(12) . .
F2 B1 N1 109.91(11) . .
F1 B1 N3 111.26(11) . .
F2 B1 N3 110.13(12) . .
N1 B1 N3 100.04(12) . .
N2 C1 N4 123.01(12) . .
N2 C1 C14 117.80(12) . .
N4 C1 C14 118.38(12) . .
C3 C2 C7 121.11(14) . .
C3 C2 N1 119.60(14) . .
C7 C2 N1 119.29(14) . .
C2 C3 C4 119.03(16) . .
C2 C3 H3 120.5 . .
C4 C3 H3 120.5 . .
C5 C4 C3 120.11(17) . .
C5 C4 H4 119.9 . .
C3 C4 H4 119.9 . .
C6 C5 C4 120.55(15) . .
C6 C5 H5 119.7 . .
C4 C5 H5 119.7 . .
C5 C6 C7 120.23(17) . .
C5 C6 H6 119.9 . .
C7 C6 H6 119.9 . .
C2 C7 C6 118.93(17) . .
C2 C7 H7 120.5 . .
C6 C7 H7 120.5 . .
C9 C8 C13 120.51(12) . .
C9 C8 N3 119.40(12) . .
C13 C8 N3 119.95(13) . .
C10 C9 C8 119.49(13) . .
C10 C9 H9 120.3 . .
C8 C9 H9 120.3 . .
C9 C10 C11 121.04(14) . .
C9 C10 H10 119.5 . .
C11 C10 H10 119.5 . .
C12 C11 C10 118.15(12) . .
C12 C11 C20 120.45(13) . .
C10 C11 C20 121.30(14) . .
C13 C12 C11 121.29(14) . .
C13 C12 H12 119.4 . .
C11 C12 H12 119.4 . .
C12 C13 C8 119.35(14) . .
C12 C13 H13 120.3 . .
C8 C13 H13 120.3 . .
C15 C14 C19 119.15(13) . .
C15 C14 C1 119.74(13) . .
C19 C14 C1 121.08(12) . .
C16 C15 C14 120.32(14) . .
C16 C15 H15 119.8 . .
C14 C15 H15 119.8 . .
C17 C16 C15 120.17(14) . .
C17 C16 H16 119.9 . .
C15 C16 H16 119.9 . .
C18 C17 C16 119.82(14) . .
C18 C17 H17 120.1 . .
C16 C17 H17 120.1 . .
C17 C18 C19 120.47(14) . .
C17 C18 H18 119.8 . .
C19 C18 H18 119.8 . .
C18 C19 C14 120.06(13) . .
C18 C19 H19 120.0 . .
C14 C19 H19 120.0 . .
C21 C20 C11 174.28(16) . .
C20 C21 Pt1 177.62(13) . .
C23 C22 P1 115.41(11) . .
C23 C22 H22A 108.4 . .
P1 C22 H22A 108.4 . .
C23 C22 H22B 108.4 . .
P1 C22 H22B 108.4 . .
H22A C22 H22B 107.5 . .
C24 C23 C22 111.94(15) . .
C24 C23 H23A 109.2 . .
C22 C23 H23A 109.2 . .
C24 C23 H23B 109.2 . .
C22 C23 H23B 109.2 . .
H23A C23 H23B 107.9 . .
C25 C24 C23 113.64(17) . .
C25 C24 H24A 108.8 . .
C23 C24 H24A 108.8 . .
C25 C24 H24B 108.8 . .
C23 C24 H24B 108.8 . .
H24A C24 H24B 107.7 . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C27 C26 P1 118.43(11) . .
C27 C26 H26A 107.7 . .
P1 C26 H26A 107.7 . .
C27 C26 H26B 107.7 . .
P1 C26 H26B 107.7 . .
H26A C26 H26B 107.1 . .
C26 C27 C28 110.89(13) . .
C26 C27 H27A 109.5 . .
C28 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
C28 C27 H27B 109.5 . .
H27A C27 H27B 108.0 . .
C29 C28 C27 113.69(14) . .
C29 C28 H28A 108.8 . .
C27 C28 H28A 108.8 . .
C29 C28 H28B 108.8 . .
C27 C28 H28B 108.8 . .
H28A C28 H28B 107.7 . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C31 C30 P1 116.56(11) . .
C31 C30 H30A 108.2 . .
P1 C30 H30A 108.2 . .
C31 C30 H30B 108.2 . .
P1 C30 H30B 108.2 . .
H30A C30 H30B 107.3 . .
C30 C31 C32 110.90(14) . .
C30 C31 H31A 109.5 . .
C32 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
C32 C31 H31B 109.5 . .
H31A C31 H31B 108.0 . .
C33 C32 C31 113.58(16) . .
C33 C32 H32A 108.8 . .
C31 C32 H32A 108.8 . .
C33 C32 H32B 108.8 . .
C31 C32 H32B 108.8 . .
H32A C32 H32B 107.7 . .
C32 C33 H33A 109.5 . .
C32 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C32 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C21 1.9924(14) .
Pt1 C21 1.9924(14) 2_766
Pt1 P1 2.3026(7) 2_766
Pt1 P1 2.3026(7) .
P1 C22 1.8238(16) .
P1 C26 1.8256(16) .
P1 C30 1.8310(18) .
F1 B1 1.3703(19) .
F2 B1 1.3820(19) .
N1 N2 1.3137(18) .
N1 C2 1.4305(18) .
N1 B1 1.554(2) .
N2 C1 1.3409(18) .
N3 N4 1.3122(17) .
N3 C8 1.4234(16) .
N3 B1 1.5576(19) .
N4 C1 1.3504(17) .
C1 C14 1.478(2) .
C2 C3 1.386(2) .
C2 C7 1.392(2) .
C3 C4 1.396(2) .
C3 H3 0.9500 .
C4 C5 1.383(3) .
C4 H4 0.9500 .
C5 C6 1.377(3) .
C5 H5 0.9500 .
C6 C7 1.396(2) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 C9 1.393(2) .
C8 C13 1.395(2) .
C9 C10 1.3882(18) .
C9 H9 0.9500 .
C10 C11 1.403(2) .
C10 H10 0.9500 .
C11 C12 1.402(2) .
C11 C20 1.4326(18) .
C12 C13 1.3853(19) .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 C15 1.3970(19) .
C14 C19 1.398(2) .
C15 C16 1.390(2) .
C15 H15 0.9500 .
C16 C17 1.386(2) .
C16 H16 0.9500 .
C17 C18 1.386(2) .
C17 H17 0.9500 .
C18 C19 1.388(2) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C21 1.2170(19) .
C22 C23 1.528(2) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C24 1.524(2) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.519(3) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 C27 1.516(2) .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 C28 1.532(2) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 C29 1.503(3) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 C31 1.524(2) .
C30 H30A 0.9900 .
C30 H30B 0.9900 .
C31 C32 1.532(3) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C33 1.520(3) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C2 N1 N2 C1 161.78(12)
B1 N1 N2 C1 -18.29(18)
C8 N3 N4 C1 -163.40(12)
B1 N3 N4 C1 16.51(18)
N2 N1 B1 F1 164.78(12)
C2 N1 B1 F1 -15.30(19)
N2 N1 B1 F2 -69.19(16)
C2 N1 B1 F2 110.73(15)
N2 N1 B1 N3 46.66(15)
C2 N1 B1 N3 -133.43(13)
N4 N3 B1 F1 -164.91(12)
C8 N3 B1 F1 14.99(19)
N4 N3 B1 F2 69.76(16)
C8 N3 B1 F2 -110.35(14)
N4 N3 B1 N1 -45.92(15)
C8 N3 B1 N1 133.98(13)
N1 N2 C1 N4 -21.5(2)
N1 N2 C1 C14 169.03(12)
N3 N4 C1 N2 22.4(2)
N3 N4 C1 C14 -168.19(12)
N2 N1 C2 C3 149.65(13)
B1 N1 C2 C3 -30.26(19)
N2 N1 C2 C7 -29.53(18)
B1 N1 C2 C7 150.55(14)
C7 C2 C3 C4 1.5(2)
N1 C2 C3 C4 -177.64(12)
C2 C3 C4 C5 0.3(2)
C3 C4 C5 C6 -1.3(2)
C4 C5 C6 C7 0.5(3)
C3 C2 C7 C6 -2.3(2)
N1 C2 C7 C6 176.85(13)
C5 C6 C7 C2 1.3(2)
N4 N3 C8 C9 -141.34(13)
B1 N3 C8 C9 38.76(19)
N4 N3 C8 C13 34.40(18)
B1 N3 C8 C13 -145.50(14)
C13 C8 C9 C10 -3.5(2)
N3 C8 C9 C10 172.21(12)
C8 C9 C10 C11 0.3(2)
C9 C10 C11 C12 3.2(2)
C9 C10 C11 C20 -173.11(13)
C10 C11 C12 C13 -3.5(2)
C20 C11 C12 C13 172.85(14)
C11 C12 C13 C8 0.3(2)
C9 C8 C13 C12 3.2(2)
N3 C8 C13 C12 -172.47(13)
N2 C1 C14 C15 -3.4(2)
N4 C1 C14 C15 -173.38(13)
N2 C1 C14 C19 178.80(13)
N4 C1 C14 C19 8.8(2)
C19 C14 C15 C16 0.1(2)
C1 C14 C15 C16 -177.72(14)
C14 C15 C16 C17 0.0(2)
C15 C16 C17 C18 -0.5(2)
C16 C17 C18 C19 0.9(2)
C17 C18 C19 C14 -0.8(2)
C15 C14 C19 C18 0.3(2)
C1 C14 C19 C18 178.08(14)
C26 P1 C22 C23 64.61(13)
C30 P1 C22 C23 169.56(12)
Pt1 P1 C22 C23 -65.85(13)
P1 C22 C23 C24 166.15(12)
C22 C23 C24 C25 -178.66(15)
C22 P1 C26 C27 -90.66(14)
C30 P1 C26 C27 161.52(13)
Pt1 P1 C26 C27 41.04(14)
P1 C26 C27 C28 -166.22(11)
C26 C27 C28 C29 177.85(15)
C22 P1 C30 C31 64.68(14)
C26 P1 C30 C31 175.07(13)
Pt1 P1 C30 C31 -62.78(13)
P1 C30 C31 C32 179.06(12)
C30 C31 C32 C33 179.67(17)
