Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes.
Authors of publication
Mason, Kevin; Harnden, Alice C.; Patrick, Connor W.; Poh, Adeline W. J.; Batsanov, Andrei S.; Suturina, Elizaveta A.; Vonci, Michele; McInnes, Eric J. L.; Chilton, Nicholas F.; Parker, David
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2018
Journal volume
54
Journal issue
61
Pages of publication
8486 - 8489
a
7.6574 ± 0.0003 Å
b
13.1494 ± 0.0005 Å
c
22.747 ± 0.0009 Å
α
86.53 ± 0.002°
β
86.957 ± 0.002°
γ
74.094 ± 0.002°
Cell volume
2197.08 ± 0.15 Å3
Cell temperature
160 K
Ambient diffraction temperature
160 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0444
Residual factor for significantly intense reflections
0.0315
Weighted residual factors for significantly intense reflections
0.0619
Weighted residual factors for all reflections included in the refinement
0.064
Goodness-of-fit parameter for all reflections included in the refinement
