Information card for entry 7122011

Structure parameters

• Chemical name: Chloridodifluorido-(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)gold(III)
• Formula: C21 H26 Au Cl F2 N2
• Calculated formula: C21 H26 Au Cl F2 N2
• Title of publication: Tuning the Lewis acidity of difluorido gold(iii) complexes: the synthesis of [AuClF₂(SIMes)] and [AuF₂(OTeF₅)(SIMes)].
• Authors of publication: Ellwanger, Mathias A.; von Randow, Clara; Steinhauer, Simon; Zhou, Yunfei; Wiesner, Anja; Beckers, Helmut; Braun, Thomas; Riedel, Sebastian
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 67
• Pages of publication: 9301 - 9304
• a: 14.7369 ± 0.0009 Å
• b: 20.2843 ± 0.0014 Å
• c: 7.0652 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2112 ± 0.2 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110.04 K
• Number of distinct elements: 6
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.0234
• Residual factor for significantly intense reflections: 0.0203
• Weighted residual factors for significantly intense reflections: 0.0435
• Weighted residual factors for all reflections included in the refinement: 0.0444
• Goodness-of-fit parameter for all reflections included in the refinement: 1.118
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No