Information card for entry 7122057

Structure parameters

• Formula: C39 H66 Cl N5 Ni O5 Si2
• Calculated formula: C39 H66 Cl N5 Ni O5 Si2
• Title of publication: Metal nitrene-like reactivity of a Si[double bond, length as m-dash]N bond towards CO₂.
• Authors of publication: Hadlington, Terrance J.; Szilvási, Tibor; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 67
• Pages of publication: 9352 - 9355
• a: 13.8284 ± 0.0002 Å
• b: 14.3306 ± 0.0002 Å
• c: 24.1972 ± 0.0003 Å
• α: 90°
• β: 104.6 ± 0.002°
• γ: 90°
• Cell volume: 4640.3 ± 0.12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0382
• Weighted residual factors for significantly intense reflections: 0.1013
• Weighted residual factors for all reflections included in the refinement: 0.1121
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No