Information card for entry 7122334

Structure parameters

• Common name: U(N2CPh2)(TIG)3
• Formula: C57 H106 N11 U
• Calculated formula: C57 H106 N11 U
• Title of publication: Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane.
• Authors of publication: Settineri, Nicholas S.; Shiau, Angela A.; Arnold, John
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 77
• Pages of publication: 10913 - 10916
• a: 12.3599 ± 0.0006 Å
• b: 12.6609 ± 0.0006 Å
• c: 21.029 ± 0.0011 Å
• α: 88.8639 ± 0.0011°
• β: 77.3174 ± 0.0011°
• γ: 79.3741 ± 0.0011°
• Cell volume: 3154.7 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0376
• Residual factor for significantly intense reflections: 0.0315
• Weighted residual factors for significantly intense reflections: 0.0726
• Weighted residual factors for all reflections included in the refinement: 0.075
• Goodness-of-fit parameter for all reflections included in the refinement: 1.115
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No