Information card for entry 7122965

Structure parameters

• Formula: C23 H52 N2 O2 P2 Pt
• Calculated formula: C23 H52 N2 O2 P2 Pt
• Title of publication: Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid
• Authors of publication: Szynkiewicz, Natalia; Ponikiewski, Łukasz; Grubba, Rafał
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 18.1821 ± 0.001 Å
• b: 17.6525 ± 0.0007 Å
• c: 17.7026 ± 0.001 Å
• α: 90°
• β: 97.794 ± 0.004°
• γ: 90°
• Cell volume: 5629.3 ± 0.5 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0641
• Residual factor for significantly intense reflections: 0.0516
• Weighted residual factors for significantly intense reflections: 0.1312
• Weighted residual factors for all reflections included in the refinement: 0.1383
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No