Information card for entry 7124563

Structure parameters

• Common name: Os(ONO)2 . 2 CHCl3
• Chemical name: Bis[bis(3,5-di-tert-butyl-2-oxyphenyl)amido]osmium dichloroform solvate
• Formula: C58 H82 Cl6 N2 O4 Os
• Calculated formula: C56.5 H80.5 Cl1.5 N2 O4 Os
• Title of publication: Octahedral to trigonal prismatic distortion driven by subjacent orbital π antibonding interactions and modulated by ligand redox noninnocence.
• Authors of publication: Cipressi, Jacqueline; Brown, Seth N.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2014
• Journal volume: 50
• Journal issue: 59
• Pages of publication: 7956 - 7959
• a: 59.4673 ± 0.0019 Å
• b: 21.5249 ± 0.0006 Å
• c: 19.0986 ± 0.0005 Å
• α: 90°
• β: 95.211 ± 0.003°
• γ: 90°
• Cell volume: 24345.7 ± 1.2 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0689
• Residual factor for significantly intense reflections: 0.0595
• Weighted residual factors for significantly intense reflections: 0.1458
• Weighted residual factors for all reflections included in the refinement: 0.1506
• Goodness-of-fit parameter for all reflections included in the refinement: 1.055
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No