Information card for entry 7126043

Structure parameters

• Formula: C52 H45 Cl9 P4 Rh2
• Calculated formula: C52 H45 Cl9 P4 Rh2
• SMILES: [Rh]234([Cl][Rh](Cl)(Cl)([P](c1ccccc1)(c1ccccc1)C[P]2(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)C[P]3(c1ccccc1)c1ccccc1)=[C]=4Cl)(Cl)Cl.ClC(Cl)Cl
• Title of publication: Semi-bridging σ-Silyls as Z-type Ligands
• Authors of publication: Hill, Anthony; Sharma, Manab; Sinha, Arup; Ward, Jas S.; Frogley, Benjamin
• Journal of publication: Chemical Communications
• Year of publication: 2020
• a: 10.9452 ± 0.0005 Å
• b: 14.1036 ± 0.0007 Å
• c: 23.4931 ± 0.0008 Å
• α: 81.467 ± 0.004°
• β: 76.544 ± 0.003°
• γ: 69.731 ± 0.004°
• Cell volume: 3299.5 ± 0.3 ų
• Cell temperature: 150 ± 0.1 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1193
• Residual factor for significantly intense reflections: 0.0798
• Weighted residual factors for significantly intense reflections: 0.1969
• Weighted residual factors for all reflections included in the refinement: 0.2233
• Goodness-of-fit parameter for all reflections included in the refinement: 1.07
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No