Information card for entry 7126122

Structure parameters

• Formula: C25 H24 Cl N Si
• Calculated formula: C25 H24 Cl N Si
• SMILES: Clc1c(C([Si](c2ccccc2)(C)C)Cc2nc3c(cc2)cccc3)cccc1
• Title of publication: Copper-catalyzed asymmetric silyl addition to alkenyl-substituted N-heteroarenes.
• Authors of publication: Zeng, Ya-Li; Chen, Bo; Wang, Ya-Ting; He, Cheng-Yu; Mu, Zi-Yuan; Du, Ji-Yuan; He, Long; Chu, Wen-Dao; Liu, Quan-Zhong
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 11
• Pages of publication: 1693 - 1696
• a: 8.346 ± 0.004 Å
• b: 9.916 ± 0.004 Å
• c: 13.969 ± 0.006 Å
• α: 86.705 ± 0.012°
• β: 77.173 ± 0.011°
• γ: 71.341 ± 0.014°
• Cell volume: 1067.8 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293.15 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0547
• Residual factor for significantly intense reflections: 0.041
• Weighted residual factors for significantly intense reflections: 0.0952
• Weighted residual factors for all reflections included in the refinement: 0.1025
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0688
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No