Information card for entry 7126585

Structure parameters

• Formula: C16 H30 B N Si2 W
• Calculated formula: C16 H30 B N Si2 W
• SMILES: [WH2]12345678([c]9(BN([Si](C)(C)C)[Si](C)(C)C)[cH]1[cH]2[cH]3[cH]49)[cH]1[cH]5[cH]6[cH]7[cH]81
• Title of publication: Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds.
• Authors of publication: Liu, Siyuan; Légaré, Marc-André; Hofmann, Alexander; Dellermann, Theresa; Braunschweig, Holger
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 53
• Pages of publication: 7277 - 7280
• a: 9.1544 ± 0.0009 Å
• b: 13.25 ± 0.002 Å
• c: 17.443 ± 0.003 Å
• α: 99.524 ± 0.008°
• β: 102.213 ± 0.005°
• γ: 106.236 ± 0.004°
• Cell volume: 1927.7 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0495
• Residual factor for significantly intense reflections: 0.0347
• Weighted residual factors for significantly intense reflections: 0.0526
• Weighted residual factors for all reflections included in the refinement: 0.0577
• Goodness-of-fit parameter for all reflections included in the refinement: 1.079
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No