Information card for entry 7126624

Structure parameters

• Formula: C27 H47 Au F6 N3 Sb Si3
• Calculated formula: C27 H47 Au F6 N3 Sb Si3
• SMILES: [Au]1([Si]2([N](=C(N2C(C)(C)C)c2ccccc2)C(C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[cH]2[cH]1cccc2.[Sb](F)(F)(F)(F)([F-])F
• Title of publication: N-Heterocyclic silylene/germylene ligands in Au(i) catalysis.
• Authors of publication: Parvin, Nasrina; Mishra, Bijoyananda; George, Anjana; Neralkar, Mahesh; Hossain, Jabed; Parameswaran, Pattiyil; Hotha, Srinivas; Khan, Shabana
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 55
• Pages of publication: 7625 - 7628
• a: 11.831 ± 0.007 Å
• b: 21.434 ± 0.014 Å
• c: 14.563 ± 0.01 Å
• α: 90°
• β: 98.575 ± 0.018°
• γ: 90°
• Cell volume: 3652 ± 4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0649
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0622
• Weighted residual factors for all reflections included in the refinement: 0.0708
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No