Information card for entry 7127066

Structure parameters

• Formula: C97 H152 N2 O Si7
• Calculated formula: C97 H152 N2 O Si7
• Title of publication: Nickel-assisted complete cleavage of CO by a silylene/siliconoid hybrid under formation of an Si[double bond, length as m-dash]C enol ether bridge.
• Authors of publication: Poitiers, Nadine E.; Huch, Volker; Zimmer, Michael; Scheschkewitz, David
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 74
• Pages of publication: 10898 - 10901
• a: 13.0001 ± 0.0003 Å
• b: 28.8076 ± 0.0008 Å
• c: 26.4244 ± 0.0006 Å
• α: 90°
• β: 93.4546 ± 0.0009°
• γ: 90°
• Cell volume: 9878 ± 0.4 ų
• Cell temperature: 133 ± 2 K
• Ambient diffraction temperature: 133 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0613
• Residual factor for significantly intense reflections: 0.0492
• Weighted residual factors for significantly intense reflections: 0.1436
• Weighted residual factors for all reflections included in the refinement: 0.1541
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No