Information card for entry 7128324

Structure parameters

• Formula: C28 H55 B10 N4 O3 P Si
• Calculated formula: C28 H55 B10 N4 O3 P Si
• Title of publication: Distinctly different reactivity of bis(silylenyl)-<i>versus</i> phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards O₂, N₂O and CO₂.
• Authors of publication: Xiong, Yun; Yao, Shenglai; Ruzicka, Ales; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2021
• Journal volume: 57
• Journal issue: 48
• Pages of publication: 5965 - 5968
• a: 16.6462 ± 0.0007 Å
• b: 15.4729 ± 0.0005 Å
• c: 16.1445 ± 0.0007 Å
• α: 90°
• β: 117.67 ± 0.006°
• γ: 90°
• Cell volume: 3682.7 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0746
• Residual factor for significantly intense reflections: 0.0523
• Weighted residual factors for significantly intense reflections: 0.1333
• Weighted residual factors for all reflections included in the refinement: 0.1546
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No