Information card for entry 7130658

Structure parameters

• Formula: C52 H148 As4 Cl4 N16 Na5.34 O192 Rh5.66 S2 W40
• Calculated formula: C52 H48 As4 Cl4 N16 Na5.34 O146 Rh5.66 S2 W40
• Title of publication: An intriguing tetranuclear Rh-based polyoxometalate for the reduction of nitroarene and oxidation of aniline.
• Authors of publication: Chen, Wenjing; Li, Huafeng; Jin, Yuzhen; Wu, Che; Yuan, Zelong; Ma, Pengtao; Wang, Jingping; Niu, Jingyang
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2022
• Journal volume: 58
• Journal issue: 71
• Pages of publication: 9902 - 9905
• a: 41.05 ± 0.005 Å
• b: 19.763 ± 0.002 Å
• c: 29.763 ± 0.004 Å
• α: 90°
• β: 110.885 ± 0.005°
• γ: 90°
• Cell volume: 22559 ± 5 ų
• Cell temperature: 296 K
• Ambient diffraction temperature: 296.3 K
• Number of distinct elements: 10
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0579
• Residual factor for significantly intense reflections: 0.0402
• Weighted residual factors for significantly intense reflections: 0.0987
• Weighted residual factors for all reflections included in the refinement: 0.1101
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No