Information card for entry 7131885

Structure parameters

• Common name: (Diso)2OsPPh3 . 2 CH2Cl2
• Chemical name: Bis(N-(2,6-diisopropylphenyl)-4,6-di-tert-butyl-1,2-benzoiminoxolene)- (triphenylphosphine)osmium dichloromethane solvate
• Formula: C72 H93 Cl4 N2 O2 Os P
• Calculated formula: C71 H91 Cl2 N2 O2 Os P
• Title of publication: Slip to π Ru: structural distortions due to metal-iminoxolene π bonding.
• Authors of publication: Ayson, Patricia Rose H.; Brown, Seth N.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2023
• Journal volume: 59
• Journal issue: 63
• Pages of publication: 9618 - 9621
• a: 11.6271 ± 0.0013 Å
• b: 15.7458 ± 0.0018 Å
• c: 20.984 ± 0.002 Å
• α: 101.733 ± 0.0016°
• β: 101.092 ± 0.0016°
• γ: 107.493 ± 0.0016°
• Cell volume: 3452.8 ± 0.6 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0273
• Residual factor for significantly intense reflections: 0.0239
• Weighted residual factors for significantly intense reflections: 0.0613
• Weighted residual factors for all reflections included in the refinement: 0.0626
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No