Information card for entry 7132374

Structure parameters

• Formula: C190 H142 Cl2 N4 O8 P4 Rh2
• Calculated formula: C190 H142 Cl2 N4 O8 P4 Rh2
• Title of publication: Evolution of a 'privileged' P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C-C bond formation.
• Authors of publication: Leinauer, Luisa; Parla, Giorgio; Messelbeger, Julian; Herrera, Alberto; Heinemann, Frank W.; Langer, Jens; Chuchelkin, Ilya; Grasruck, Alexander; Frieß, Sibylle; Chelouan, Ahmed; Gavrilov, Konstantin; Dorta, Romano
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2023
• a: 12.44859 ± 0.0001 Å
• b: 37.3327 ± 0.0002 Å
• c: 16.40694 ± 0.00015 Å
• α: 90°
• β: 102.295 ± 0.0008°
• γ: 90°
• Cell volume: 7450.06 ± 0.1 ų
• Cell temperature: 100 ± 0.2 K
• Ambient diffraction temperature: 100 ± 0.2 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0527
• Residual factor for significantly intense reflections: 0.05
• Weighted residual factors for significantly intense reflections: 0.1298
• Weighted residual factors for all reflections included in the refinement: 0.1315
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No