Information card for entry 7132582

Structure parameters

• Formula: C25 H21 Co F O4 P
• Calculated formula: C25 H21 Co F O4 P
• SMILES: [Co](C#[O])(C#[O])(C#[O])C#[O].[P+](F)(c1ccccc1C)(c1ccccc1C)c1ccccc1C
• Title of publication: Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones.
• Authors of publication: Pietraru, Marie-Hélène; Ponsard, Louise; Lentz, Nicolas; Thuéry, Pierre; Nicolas, Emmanuel; Cantat, Thibault
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 8
• Pages of publication: 1043 - 1046
• a: 20.3694 ± 0.001 Å
• b: 11.8516 ± 0.0006 Å
• c: 19.7496 ± 0.001 Å
• α: 90°
• β: 106.855 ± 0.0018°
• γ: 90°
• Cell volume: 4562.9 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0444
• Residual factor for significantly intense reflections: 0.0308
• Weighted residual factors for significantly intense reflections: 0.0768
• Weighted residual factors for all reflections included in the refinement: 0.0823
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No