Information card for entry 7132638

Structure parameters

• Formula: C110 H142 B4 N8 Si2
• Calculated formula: C110 H142 B4 N8 Si2
• Title of publication: Hydrosilylation of BB triple bonds: catalyst- and reductant-free construction of B-Si bonds and B₂Si heterocycles.
• Authors of publication: Brückner, Tobias; Duwe, Dario; Fantuzzi, Felipe; Heß, Merlin; Dewhurst, Rian D.; Radacki, Krzysztof; Braunschweig, Holger
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 24
• Pages of publication: 3259 - 3262
• a: 11.641 ± 0.0002 Å
• b: 12.3141 ± 0.0003 Å
• c: 17.9847 ± 0.0003 Å
• α: 95.791 ± 0.002°
• β: 101.108 ± 0.002°
• γ: 104.877 ± 0.002°
• Cell volume: 2414.05 ± 0.09 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0695
• Residual factor for significantly intense reflections: 0.0642
• Weighted residual factors for significantly intense reflections: 0.1479
• Weighted residual factors for all reflections included in the refinement: 0.1505
• Goodness-of-fit parameter for all reflections included in the refinement: 1.112
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No