Information card for entry 7133119

Structure parameters

• Formula: C109 H143 La2 N2 O P5
• Calculated formula: C109 H143 La2 N2 O P5
• SMILES: [La]123([P](c4c(N3c3c(cccc3c3ccc(cc3)C(C)(C)C)c3ccc(cc3)C(C)(C)C)ccc(c4)C)(C(C)C)C(C)C)P([La]3(P2c2c(cc(cc2C)C)C)([P](c2c(N3c3c(cccc3c3ccc(cc3)C(C)(C)C)c3ccc(cc3)C(C)(C)C)ccc(c2)C)(C(C)C)C(C)C)P1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C.O(CC)CC
• Title of publication: A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand.
• Authors of publication: Wittwer, B.; Heim, F.; Wurst, K.; Hohloch, S.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 57
• Pages of publication: 7299 - 7302
• a: 15.498 ± 0.003 Å
• b: 16.566 ± 0.004 Å
• c: 22.288 ± 0.004 Å
• α: 76.309 ± 0.006°
• β: 70.924 ± 0.006°
• γ: 69.957 ± 0.007°
• Cell volume: 5030.1 ± 1.8 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0496
• Residual factor for significantly intense reflections: 0.0346
• Weighted residual factors for significantly intense reflections: 0.0799
• Weighted residual factors for all reflections included in the refinement: 0.0869
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No