Information card for entry 7134583

Structure parameters

• Formula: C40 H60 K Li N4 O P2
• Calculated formula: C40 H60 K Li N4 O P2
• Title of publication: [(TMEDA)Li(μ-PPh2)2K(TMEDA)(THF)]: a heterobimetallic molecular lithium–potassium phosphide complex
• Authors of publication: Crabbe, Michelle H.; O’Meara, Danielle; Kennedy, Alan R.; Weetman, Catherine E.; Mulvey, Robert E.
• Journal of publication: Chemical Communications
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 52
• Pages of publication: 9436 - 9439
• a: 12.0377 ± 0.0001 Å
• b: 12.2718 ± 0.0001 Å
• c: 14.9623 ± 0.0001 Å
• α: 90.125 ± 0.001°
• β: 107.078 ± 0.001°
• γ: 100.987 ± 0.001°
• Cell volume: 2070.12 ± 0.03 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.04
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for significantly intense reflections: 0.1085
• Weighted residual factors for all reflections included in the refinement: 0.1093
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No